Corrole-stabilised nitrido complexe Corrole rings are known to be more effective in stabilising metals in high oxidation states than porphyrins.

Corrole-stabilised nitrido complexe

Corrole rings are known to be more effective in stabilising metals in high oxidation states than porphyrins. Golobkov and Gros have exploited this exclusive right to prepare Cr(V) and Cr(VI) complexe using the corrole macrocycle (G Golobkov & Z Gros Angew Chem Int ed 2003, 42, 4507). As depicted in Figure 1 the Cr(V)-nitrido web was prepared via a N-atom transfer from an Mn(V) salophene composed of several elements followed by either electrochemical or chemical oxidation to yield the

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